"What happens to the additives in oil over time, and is there any way to replenish
them?"
Over time, additives are depleted performing the function for
which they were intended, degraded by hydrolysis, mechanical
shearing, condensation settling, water washing, particle
scrubbing, etc.
The rate of depletion or degradation depends upon the
application and the environment. In particular, heat, pressure,
shear rate, fuel sulfur, soot, dirt, water, aeration and the
presence of catalytic metals (copper, iron, etc.) affect the
rate of depletion.
Regarding replenishment - whenever you top-up a system,
you are replenishing additives. Likewise, one can perform a partial
drain and replacement (often referred to as bleed and feed).
A bleed and feed can work if the base oil is not degraded.
If the base oil has been degraded, adding new oil is analogous
to sending a healthy person into a room full of sick people with
the hope that his or her good health will be contagious - it
doesn't work that way. The additives in the new oil might be
compromised within the first hours of use, leaving you right
back where you started.
Casual addition of additives into a formulated oil
can be dangerous and should be avoided. When in doubt, consult
your lubricant supplier.
Drew
Troyer, Noria Corporation
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