"I've been told that surface tension plays a role in the performance of lubricating oils and hydraulic fluids. What is surface tension and what effect does it have?"
Surface tension relates to the skin-like film that a liquid develops at its surface. The fluid's resistance in allowing an object to rupture this skin is its surface tension. For instance, water has sufficient surface tension to permit a sewing needle to rest on its surface without sinking.
A new lubricating oil has relatively high surface tension, say 35 dynes/cm. However, as the oil ages and becomes contaminated, its surface tension will fall to 20 dynes/cm or lower. Researchers have found that this can have a dramatic effect on the lubricant's properties. Negative effects include: foaming problems, air release problems, demulsibility problems, loss of antirust performance, and increased leakage.
Oxidation and water contamination are perhaps the most common causes of loss of surface tension. Other contaminants that decrease surface tension include detergents, grease, floor soaps, some solvents, and retrofit additives. A standard tensiometer can be used to quickly measure the surface tension of most lubricants.
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